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Dr Sergey Bylikin

Sergey Bylikin

Profile summary

  • Faculty of Science, Technology, Engineering & Mathematics
  • School of Life, Health & Chemical Sciences

Professional biography

In 2009, I moved to the UK and changed my career from full-time teaching to full-time research. A former assistant professor at Russian State Medical Uniersity (Moscow, Russia), now I work as a Visiting Researcher at the OU. Since 2016, I also teach the S827 module "Concept to Clinic".

 

Research interests

Synthesis, structure and reactivity of Group 14 organoelement compounds.

More detailed outline of my research interests is available from my personal website.

 

Research papers
(in reverse chronological order)

48. A. A. Nikolin, E. P. Kramarova, A. G. Shipov, Yu. I. Baukov, Vad. V. Negrebetsky, D. E. Arkhipov, A. A. Korlyukov, A .A. Lagunin, S. Yu. Bylikin, A. R. Bassindale, P. G. Taylor. N,N-Bis-(dimethylfluorosilylmethyl)amides of N-organosulfonylproline and sarcosine: synthesis, structure, stereodynamic behaviour and in silico studies. // RCS Advances. 2016. Vol. 6. P. 75315–75327.

47. S. Yu. Bylikin, A. A. Korlyukov, A. G. Shipov, D. A. Arkhipov, N. A. Kalashnikova, Vad. V. Negrebetsky, Yu. I. Baukov. Regioselective chelation in the reaction of N-trimethylsilyl-N-acetylglycine N',N'-dimethylamide with chloro(chloromethyl)dimethylsilane. // Mendeleev Communications. 2015. Vol. 25. P. 114–116.

46. A. G. Shipov, E. P. Kramarova, H. Fang, D. E. Arkhipov, A. A. Nikolin, S. Yu. Bylikin, Vad. V. Negrebetsky, A. A. Korlyukov, N. A. Voronina, A. R. Bassindale, P. G. Taylor, Yu. I. Baukov. 1-Organosulfonyl-2-sila-5-piperazinones: Synthesis, molecular and crystal structure, and chemical transformations into 2-aminoacid derivatives. // J. Organometal. Chem. 2013. Vol. 741–742. P. 114–121.

45. N. A. Kalashnikova, S. Yu. Bylikin, A. A. Korlyukov, A. G. Shipov, Yu. I.. Baukov, P. G. Taylor, A. R. Bassindale. Cationic complexes of silicon and germanium with (O,S)-chelate ligands. // Dalton Trans. 2012. Vol. 41. P. 12681–12682.

44. A. A. Nikolin, E. P. Kramarova, A. G. Shipov, Yu. I. Baukov, V. V. Negrebetsky, A. A. Korlyukov, D. E. Arkhipov, A. Bowden, S. Yu. Bylikin, A. R. Bassindale, P. G. Taylor. Synthesis, Structures, and Stereodynamic Behavior of Novel Pentacoordinate Fluorosilanes: Fluorosilyl Derivatives of Proline. // Organomet. 2012. Vol. 31. P. 4988–4997.

43. D. V. Airapetyan, T. P. Murasheva, S. Yu. Bylikin, A. A. Korlyukov, A. G. Shipov, S. V. Gruner, E. P. Kramarova, Vad. V. Negrebetsky, S. A. Pogozhikh, G. Ya. Zueva, M. Yu. Antipin, Yu. I. Baukov. Trichloro- and methyldichlorogermyl monochelates and dibromo- and dichlorogermyl bischelates, the derivatives of N,N-disubstituted amides of 2-hydroxyamides. // Russ. Chem. Bull. 2012. No. 3. P. 639–648.

42. Nikolin A. A., Arkhipov D. E., Shipov A. G., Kramarova E. P., Kovalchuk N. A., Korlyukov A. A., Negrebetsky Vad. V., Baukov Yu. I., Bassindale A., Taylor P., Bowden A., Bylikin S. Yu. Pentacoordinate chlorosilanes with C,O-chelate ligands derived from N‑methyl‑N'‑organosulfonylprolinamides. // Russ. Chem. Heterocycl. Comp. 2012. Vol. 47. No. 12. P. 1565–1583.

41. Shipov A. G., Korlyukov A. A., Kramarova E. P., Arkhipov D. E., Bylikin S. Yu., Huntse Fan, Pogozhikh S. A., Murasheva T. P., Negrebetsky Vad. V., Khrustalev V. N., Ovchinnikov Yu. E., Bassindale A., Taylor P., Baukov Yu. I. Donor-stabilized pentacoordinate cationic intramolecular complexes of silicon with two (O–Si)-coorinating ligands. // Russ. J. Gen. Chem. 2011. Vol. 81. No. 12. P. 2412–2427..

40. Shipov A. G., Korlyukov A. A., Arkhipov D. E., Kramarova E. P., Negrebetsky Vad. V., Bylikin S. Yu., Nikolin A. A., Huntse Fan, Antipin M. Yu., Baukov Yu. I. Synthesis and structural characterization of the anionic chelates of hypercoordinate silicon, the derivatives of glycolic and tartaric acids. // Mendeleev Commun. 2010. Vol. 20. No. 5. P. 273–274.

39. Shipov A. G., Gruner S. V., Korlyukov A. A., Kramarova E. P., Murasheva T. P., Bylikin S. Yu., Negrebetsky Vad. V., Ivaschenko F. A., Airapetyan D. V., Zueva G. Ya., Antipin M. Yu., Baukov Yu. I. Tribromogermyl monochelates, the derivatives of N,N-disubstituted 2‑hydroxyamides. // Russ. Chem. Bull. 2010. No. 4. P. 761–770.

38. Pukhalskaya V. G., Kramarova E. P., Kozaeva L. P., Korlyukov A. A., Shipov A. G., Bylikin S. Yu., Negrebetsky Vad. V., Poryadin G. V., Baukov Yu. I. Synthesis, structure and muscarinic agonist activity of substituted N-(silatran-1-ylmethyl)acetamides. // Appl. Organomet. Chem. 2010. Vol. 24. P. 162–168.

37. Bylikin S. Yu., Shipov A. G., Kramarova E. P., Negrebetsky Vad. V., Korlyukov A. A., Baukov Yu. I., Hursthouse M. B., Male L., Bassindale A. R., Taylor P. G. O,O-Monochelate complexes of silicon and germanium halides: The derivatives of L-mandelic N,N-dimethylamide. // J. Organometal. Chem. 2009. Vol. 694. No. 2. P. 244–248.

36. Baukov Yu. I., Korlyukov A. A., Kramarova E. P., Shipov A. G., Bylikin S. Yu., Negrebetsky Vad. V., Antipin M. Yu. Hexacoordinate germanium mixed bischelates with the GeCO3Cl2 ligand environment. // Arkivoc. 2008. No. 4. P. 80–89.

35. Kramarova E. P., Shipov A. G., Negrebetsky Vad. V., Bylikin S. Yu., Komissarov E. A., Korlyukov A. A., Baukov Yu. I. Donor-stabilized germylium ions. Bis{[bis((O-Ge)chelato)bis(dimethylcarbamoylmethyloxy)]chloromethylgermylium} hexachlorodimercurate, the first bischelate cationic complex of pentacoordinate germanium with amides of 2-hydroxycarboxylic acids. // Russ. Chem. Bull. 2007. Vol. 56. No. 9. P. 1932–1933.

34. Shipov A. G., Kramarova E. P., Pogozhikh S. A., Negrebetsky Vad. V., Smirnova L. S., Artamkina O. B., Bylikin S. Yu., Ovchinnikov Yu. E., Baukov Yu. I. Synthesis, molecular and crystal structure of mono- and bischelate compounds of hypercoordinate silicon containing 2,2-dimethylbenzo[2H]-1,3-oxazin-4-ono-3-methyl C,O-chelate ligand. // Russ. Chem. Bull. 2007. Vol. 56. No. 3. P. 461–474.

33. Komissarov E. A., Korlyukov A. A., Kramarova E. P., Bylikin S. Yu., Negrebetsky Vad. V., Baukov Yu. I. Chloridobis[(2-oxoazocan-1-yl)methyl]germanium(IV) trifluoromethanesulfonate. // Acta Cryst. 2007. Vol. C63. P. m144–m146.

32. Negrebetsky Vad. V., Taylor P. G., Kramarova E. P., Bylikin S. Yu., Belavin S. Yu., Shipov A. G., Bassindale A. R., Baukov Yu. I. Structures and stereochemical non-rigidity of Si-substituted N-(dimethylsilylmethyl)- and N-(methylphenylsilylmethyl)amides and -lactams. // J. Organometal. Chem. 2006. Vol. 691. No. 19. P. 3976–3988.

31. Bylikin S. Yu., Shipov A. G., Negrebetsky Vad. V., Baukov Yu. I., Ovchinnikov Yu. E., Pogozhikh S. A., Pestunovich S. V., Belousova L. I., Belogolova E. F., Sidorkin V. F., Voronkov M. G., Pestunovich V. A., Kalikhman I., Kost D. Reaction of N-trimethylsilyl derivatives of amides and lactams with chloro(chloromethyl)dimethylstannane. Crystal and molecular structure of 1-(chlorodimethylstannylmethyl)-2-piperidone. // J. Organometal. Chem. 2006. Vol. 691. No. 4. P. 779–786.

30. Shipov A. G., Kramarova E. P., Murasheva T. P., Negrebetsky Vad. V., Bylikin S. Yu., Korlyukov A. A., Baukov Yu. I. Complexes of hypercoordinate germanium with novel five-membered monoanionic (O,O)-chelating ligands based on 2-hydroxycarboxamides. // Russ. Chem. Bull. 2005. Vol. 54. No. 9. P. 2233–2234.

29. Tandura S. N, Shumsky A. N., Ugrak B. I., Negrebetsky Vad. V, Bylikin S. Yu., Kolesnikov S. P. Stereochemical flexibility of bis(amidomethyl)dichlorogermanes. A novel dissociative mechanism of ligand exchange in neutral hexacoordinated bischelate complexes. // Organometallics. 2005. Vol. 24. P. 5227–5240.

28. Bylikin S. Yu., Shipov A. G., Kramarova E. P., Artamkina O. B., Negrebetsky Vad. V., Baukov Yu. I. Reactivity of N-(chlorodimethylgermyl)methyl and N-(chlorodimethylsilyl)methyl lactams and amides towards Grignard reagents. // Russ. J. Gen. Chem. 2004. Vol. 74. No. 9. P. 1356–1359.

27. Ladipo F. T., Sarveswaran V., Kingston J. V., Huyck R. A., Bylikin S. Yu., Carr S. D., Watts R., Parkin S. Synthesis, characterization, and alkyne cyclotrimerization chemistry of titanium complexes supported by calixarene-derived bis(aryloxide) ligation. // J. Organomet. Chem. 2004. Vol. 689. No. 3. P. 502–514.

26. Kramarova E. P., Korlyukov A. A., Bylikin S. Yu., Shipov A. G., Baukov Yu. I., Kost D. Ionic structure of the bischelate dichlorosilane stabilized by O–Si coordination, the product of reaction of N-methyl-N-trimethylsilylacetamide with (ClCH2)2SiCl2. // Russ. Chem. Bull. 2004. Vol. 53. No. 5. P. 1135–1136.

25. Kramarova E. P., Pogozhikh S. A., Shipov A. G., Negrebetsky Vad. V., Nikolaeva T. P., Bylikin S. Yu., Ovchinnikov Yu. E., Baukov Yu. I. Bis(O–Si)-chelate difluorobis{[N-(1-phenylethyl)acetamido]methyl}silane: the first stable hexacoordinated silicon compound with two C,O-chelating ligands. // Russ. Chem. Bull. 2004. Vol. 53. No. 1. P. 262–263.

24. Bylikin S. Yu., Kramarova  E. P., Pogozhikh S. A., Shipov  A. G., Negrebetsky  Vad. V., Ovchinnikov Yu. I., Baukov  Yu. I. Synthesis, molecular and crystal structures of new cation-anionic hypervalent germanium complexes with 1,1,3,3-tetrakis(O–Ge)chelato-1,1,3,3-tetra(lactamomethyl)-1,3-digermoxane dications. // Russ. Chem. Bull. 2003. Vol. 52. No. 8. P. 1720–1729.

23. Negrebetsky Vad. V., Bylikin S. Yu., Shipov A. G., Baukov Yu. I., Bassindale A. R., Taylor P. G. Stereochemical rearrangements of dibromides of hexacoordinated germanium with amido- and lactamomethyl chelate ligands. // J. Organomet. Chem. 2003. Vol. 678. No. 1–2. P. 39–47.

22. Zamyshlyaeva O. A., Shipov A. G., Kramarova E. P., Negrebetsky Vad. V., Shumsky A. N., Tandura S. N., Bylikin S. Yu., Ovchinnikov Yu. E., Pogozhikh S. A., Baukov Yu. I. Synthesis and some properties of 2,2-dimethyl-4-R-1-oxa-4-aza-2-sila-5-benzocycloheptanones. // Chem. Heterocycl. Comp. 2002. Vol. 38. No. 1. P. 116–127.

21. Bylikin S. Yu., Kramarova E. P., Shipov A. G., Negrebetsky Vad. V., Baukov Yu. I. Synthesis and thermal stability of N-(chlorodimethylgermyl)methyl-N-methyl-O-(trimethylsilyl)salicylamide. // Russ. J. Gen. Chem. 2001. Vol. 71. No. 8. P. 1323–1325.

20. Kramarova E. P., Bylikin S. Yu., Shipov A. G., Negrebetsky Vad. V., Ovchinnikov Yu. E., Pogozhikh S. A., Baukov Yu. I. Bis[di(O–Si)chelatodi(2-oxopiperidinomethyl)chloromethylsilicenium] hexachlorodimercurate, the first representative of cation-anionic complexes containing silicenium ion with three Si–C bonds, stabilized by O–Si coordination. // Russ. J. Gen. Chem. 2001. Vol. 71. No. 8. P. 1321–1322.

19. Kramarova E. P., Pogozhikh S. A., Shipov A. G., Negrebetsky Vad. V., Tandura S. N., Shumsky A. N., Artamkin S. A., Bylikin S. Yu., Ovchinnikov Yu. E., Baukov Yu. I. Bis(O–Si)-chelate fluorobis(2-oxohexahydroazepinomethyl)silylium tetrafluoroborate, a cation-anionic complex containing a silylium ion stabilized by O–Si coordination. // Russ. Chem. Bull. 2001. Vol. 50. No. 2. P. 331–332.

18. Bylikin S. Y., Robson D. A., Male N. A. H., Rees L. H., Mountford P., Schroeder M. New main group and early transition metal complexes of mono-pendant arm triazacyclononane ligands. // Dalton Trans. 2001. No. 2. P. 170–180.

17. Robson D. A., Bylikin S. Y., Cantuel M., Male N. A. H., Rees L. H., Mountford P., Schroeder M. Neutral and cationic organometallic aluminium and indium complexes of mono-pendant arm triazacyclononane ligands. // Dalton Trans. 2001. No. 2. P. 157–169.

16. Ovchinnikov Yu. E., Pogozhikh S. A., Khrustalev V. N., Bylikin S. Yu., Negrebetsky Vad. V., Shipov A. G., Baukov Yu. I. Crystal and molecular structures of six-coordinate germanium difluorides and dibromides containing lactamomethyl C,O-chelating ligands. // Russ. Chem. Bull. 2000. Vol. 49. No. 10. P. 1775–1781.

15. Bylikin S. Yu., Pogozhikh S. A., Shipov A. G., Negrebetskii Vad. V., Ovchinnikov Yu. E., Baukov Yu. I. Unexpected formation of a dimeric cation-anionic complex of hypercoordinated tin in the reaction of bis[(2-oxopyrrolidino)methyl]tin dichloride with AgBF4. // Russ. Chem. Bull. 2000. Vol. 49. No. 4. P. 755–757.

14. Male N. A. H., Skinner M. E. G., Bylikin S. Yu., Wilson P. J., Mountford P., Schroeder M. Macrocycle-supported titanium complexes with chelating imido ligands: Analogues of ansa-metallocenes. // Inorg. Chem. 2000. Vol. 39. No. 24. P. 5483–5491.

13. Pogozhikh S. A., Ovchinnikov Yu. E., Bylikin S. Yu., Negrebetsky Vad. V., Shipov A. G., Baukov Yu. I. Synthesis, crystal and molecular structure and stereochemical non-rigidity of bis[(N-methylacetamido)methyl]dichlorogermane and -dichlorostannane. // Russ. J. Gen. Chem. 2000. Vol. 70. No. 4. P. 533–538.

12. Bylikin S. Yu., Pogozhikh S. A., Khrustalev V. N., Negrebetsky Vad.V., Shipov A. G., Ovchinnikov Y. E., Baukov Yu. I. Synthesis, crystal and molecular structures, and stereochemical non-rigidity of N-(chlorodimethylgermylmethyl)- and N-(bromodimethylgermylmethyl)-N-[(S)-1-phenylethyl]acetamides and N-(chlorodimethylgermylmethyl)-4-phenyl-2-pyrrolidone. // Russ. Chem. Bull. 2000. Vol. 49. No. 1. P. 140–147.

11. Ovchinnikov Yu. E., Pogozhikh S. A., Razumovskaya I. V., Bylikin S. Yu., Shipov A. G., Smirnova L. S., Negrebetsky Vad. V., Baukov Yu. I. Synthesis, crystal and molecular structure of six-coordinate tin dibromides and diiodides containing lactamomethyl C,O-chelating ligands. // Russian Chemical Bulletin. 1999. Vol. 48. No. 10. 1964–1974.

10. Ovchinnikov Yu. E., Pogozhikh S. A., Razumovskaya I. V., Shipov A. G., Kramarova E. P., Bylikin S. Yu., Negrebetsky Vad. V., Baukov Yu. I. Synthesis, crystal and molecular structure of cation-anionic complexes of five-coordinated silicon containing disiloxane dications with lactamomethyl and N-methylacetamidomethyl C,O-chelating ligands. // Russian Chemical Bulletin. 1998. Vol. 47. No. 5. P. 967–978.

9. Kurochka A. V., Agafonova O. V., Losev A. S., Mamaeva E. A., Bylikin S. Yu., Negrebetsky Vad. V., Kramarova E. P., Shipov A. G., Baukov Yu. I. Six- and seven-membered 1-oxa-4-aza-2-silacyclanes as possible correctors of adaptational mechanisms. // Metal Based Drugs. 1998. Vol. 5. No. 1. P. 25–33.

8. Bylikin S. Yu., Shipov A. G., Kramarova E. P., Negrebetsky Vad. V., Smirnova L. S., Pogozhikh C. A., Ovchinnikov Yu. E., Baukov Yu. I. Features of nucleophilic substitution at six-coordinate germanium atom in (O–Ge)bischelate bis(lactamomethyl)dichlorogermanes. // Russ. J. Gen. Chem. 1997. Vol. 67. No. 11. P. 1742–1756.

7. Bylikin S. Yu., Shipov A. G., Negrebetsky Vad. V., Smirnova L. S., Baukov Yu. I., Ovchinnikov Yu. E., Struchkov Yu. T. Synthesis, crystal structure and stereochemical non-rigidity of (O–Sn)-bischelated bis(lactamomethyl)dichlorostannanes. // Russian Chemical Bulletin. 1996. Vol. 45. No. 11. P. 2627–2638.

6. Shipov A. G., Bylikin S. Yu., Negrebetsky Vad. V., Baukov Yu. I. Direct synthesis of bis(O–Sn)-chelate bis(lactamo-N-methyl)dichlorostannanes. // Zhurnal Obshchey Khimii. 1995. Vol. 65. No. 12. P. 2066–2067 (in Russian).

5. Ovchinnikov Yu. E., Struchkov Yu. T., Baukov Yu. I., Shipov A. G., Bylikin S. Yu. Structures of organic derivatives of hexacoordinated germanium. (O–Ge)-chelated bis(2-oxo-1-hexahydroazepinylmethyl)difluorogermane and bis-(2-oxo-1-hexahydroazepinylmethyl)fluorogermane tetrafluoroborate. // Russian Chemical Bulletin. 1994. Vol. 43. No. 8. P. 1351–1355.

4. Ovchinnikov Yu. E., Struchkov Yu. T., Baukov Yu. I., Shipov A. G., Kramarova E. P., Bylikin S. Yu. Structures of organic derivatives of hexacoordinated germanium. (O–Ge)-chelated bis(2-oxo-1-hexahydroazepinylmethyl)chlorogermane iodide and bis-(2-oxo-1-hexahydroazepinylmethyl)chlorogermane triiodide. // Russ. Chem. Bull. 1994. Vol. 43. No. 8. P. 1346–1350.

3. Ovchinnikov Yu. E., Struchkov Yu. T., Shipov A. G., Smirnova L. S., Baukov Yu. I., Bylikin S. Yu. Modelling of hexacoordinated transition states of germanium based on the crystal structures of germanium-substituted bis(lactamo-N-methyl)germanes L2GeX2 and L2GeXY (X, Y = Hal, OTf, BF4, I3). // Mendeleev Commun. 1994. No. 5. P. 178–180.

2. Baukov Yu. I., Shipov A. G., Smirnova L. S., Kramarova E. P., Bylikin S. Yu., Ovchinnikov Yu. E., Struchkov Yu. T. Interaction of the (O–Ge)-chelate bis-(lactamo-N-methyl)-cis-dichlorogermanes with trimethylsilyl triflate. Synthesis of bis(lactamo-N-methyl)-trans-(trifluoromethylsulfonyloxy)chlorogermanes. // J. Organomet. Chem. 1993. Vol. 461. No. 1–2. P. 39–42.

1. Shipov A. G., Kramarova E. P., Bylikin S. Yu., Mamaeva E. A., Zaitseva G. S., Sergeev V. N., Baukov Yu. I. Synthesis of six- and seven-membered 1-oxa-4-aza-2-sila heterocycles from O-(trimethylsilyl) derivatives of N-monosubstituted amides of 2-hydroxy carboxylic and o-phenolic acids and chloro(chloromethyl)dimethylsilane. // Zh. Obshch. Khim. 1993. Vol. 63. No. 5. P. 1195–1196 (in Russian).

 

Teaching interests

General, Organic, Bio-organic, and Physical chemistry for undergraduate students.

 

Selected academic publications

1. Lensky A. S., Belavin I. Yu., Bylikin S. Yu. Biophysical and Bioinorganic Chemistry. Moscow, "MIA Publishing", 2009. ISBN 978-5-8948-1681-4 (in Russian).

2. Bylikin S. Yu. General and Bioorganic Chemistry. Workbook for foreign students. Moscow, "MIA Publishing", 2009 (in English).

3. Bylikin S. Yu. General and Bioorganic Chemistry. Workbook for foreign students. Moscow, "MIA Publishing", 2009 (in English).

 

Other acedemic publications are available from my author's page at Amazon.

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